SECURITIES
      AND EXCHANGE COMMISSION
    Washington,
      D.C. 20549
     
    FORM
      8-K
     
    CURRENT
      REPORT
    PURSUANT
      TO SECTION 13 OR 15(d) OF
    THE
      SECURITIES EXCHANGE ACT OF 1934
    
    
      
          
            | 
                 
              Date
                of Report (Date of earliest event reported) 
             | 
            
                 
              October
                17, 2006 
             | 
          
          
            | 
                 
              PACIFIC
                ETHANOL, INC. 
             | 
          
          
            | 
               (Exact
                name of registrant as specified in its
                charter) 
             | 
          
      
     
     
    
      
          
            |  Delaware | 
              | 
             000-21467 | 
              | 
            41-2170618  | 
          
          
            | 
               (State
                or other jurisdiction 
              of
                incorporation) 
             | 
              | 
            
               (Commission
                File Number) 
             | 
              | 
            
               (IRS
                Employer 
              Identification
                No.) 
             | 
          
      
     
     
    
      
          
            | 
                 
              5711
                N. West Avenue, Fresno, California 
             | 
              | 
            
                 
              93711 
             | 
          
          
            | 
               (Address
                of principal executive offices) 
             | 
              | 
            
               (Zip
                Code) 
             | 
          
          
            | 
                 
              Registrant’s
                telephone number, including area code: 
             | 
              | 
            
                 
              (559)
                435-1771 
             | 
          
      
     
     
    
      
          
            |   | 
          
          
            | 
               (Former
                name or former address, if changed since last
                report) 
             | 
          
      
     
    
    Check
      the
      appropriate box below if the Form 8-K filing is intended to simultaneously
      satisfy the filing obligation of the registrant under any of the following
      provisions (see
      General
      Instruction A.2. below):
    
    o Written
      communications pursuant to Rule 425 under the Securities Act (17 CFR
      230.425)
    
    o Soliciting
      material pursuant to Rule 14a-12 under the Exchange Act (17 CFR
      240.14a-12)
    
    o Pre-commencement
      communications pursuant to Rule 14d-2(b) under the Exchange Act (17 CFR
      240.14d-2(b))
    
    o Pre-commencement
      communications pursuant to Rule 13e-4(c) under the Exchange Act (17 CFR
      240.13e-4(c))
    
    
     
    Item
      1.01. Entry
      Into a Material Definitive Agreement.
     
    (1) Acquisition
      of Membership Units of Front Range Energy, LLC
     
    Membership
      Interest Purchase Agreement dated as of October 17, 2006 by and among Eagle
      Energy, LLC, Pacific Ethanol California, Inc. and Pacific Ethanol,
      Inc.
     
    On
      October 17, 2006, Pacific Ethanol California, Inc. (“PE California”), a
      wholly-owned subsidiary of Pacific Ethanol, Inc.(the “Company”), and the
      Company, entered into a Membership Interest Purchase Agreement (the “Purchase
      Agreement”) dated as of October 17, 2006 with Eagle Energy, LLC (“Eagle
      Energy”). Under the Purchase Agreement, PE California purchased from Eagle
      Energy 10,095 Class B Voting Units of Front Range Energy, LLC (“Front Range”)
      and thereby acquired approximately 42% of the outstanding membership interests
      of Front Range. PE California paid to Eagle Energy $30 million in cash and
      the
      Company issued to Eagle Energy 2,081,888 shares of the Company’s common stock
      and a warrant to purchase up to 693,963 shares of the Company’s common stock at
      an exercise price of $14.41 per share. The Purchase Agreement contains customary
      representations, warranties and covenants by the parties and other customary
      obligations, including those relating to indemnification and
      confidentiality.
     
    Warrant
      to Purchase Common Stock dated October 17, 2006 issued to Eagle Energy, LLC
      by
      Pacific Ethanol, Inc.
     
    On
      October 17, 2006, the Company issued a Warrant to Purchase Common Stock dated
      October 17, 2006 to Eagle Energy (the “Warrant”). Under the Warrant, Eagle
      Energy has the right to purchase up to 693,963 share of the Company’s common
      stock at an exercise price of $14.41 per share. The Warrant is exercisable
      immediately through and including October 17, 2007. The Warrant includes both
      cash and cashless exercise provisions. 
     
    Registration
      Rights Agreement dated as of October 17, 2006 by and between Pacific Ethanol,
      Inc. and Eagle Energy, LLC
     
    On
      October 17, 2006, the Company entered into a Registration Rights Agreement
      dated
      as of October 17, 2006 with Eagle Energy (the “Registration Rights Agreement”).
      The Registration Rights Agreement provides that the Company must register for
      resale by Eagle Energy the 2,081,888 shares of common stock issued to Eagle
      Energy and the 693,963 shares of common stock underlying the
      Warrant.
     
    The
      registration obligations require, among other things, that the Company file
      an
      initial registration statement with the Securities and Exchange Commission
      (“SEC”) no later than October 31, 2006 and cause the registration statement to
      be declared effective within 120 days of October 17, 2006, or earlier if the
      registration statement is not reviewed or is no longer subject to review by
      the
      SEC. If the Company is unable to meet these obligations, is unable to maintain
      the effectiveness of the registration in accordance with the requirements of
      the
      Registration Rights Agreement or is unable to satisfy certain other obligations
      under the Registration Rights Agreement, then an event of default will have
      occurred, and the upon the occurrence of such event and upon every monthly
      anniversary thereafter until such event is cured, the Company will be required
      to pay to Eagle Energy, as liquidated damages and not as a penalty, an amount
      equal to 1% of (i) the sum of the number of shares of common stock held by
      Eagle
      Energy and the shares of common stock issuable upon exercise of the Warrant
      as
      of the date of default, multiplied by (ii) the closing market price of the
      Company’s common stock on such date; provided, that the maximum aggregate amount
      of such damages is not to exceed $3 million.
     
     
    
     
    The
      Registration Rights Agreement contains customary covenants and obligations
      on
      the part of the Company and Eagle Energy, including various indemnification
      provisions in connection with the offering and registration of the shares of
      common stock issued to Eagle Energy and shares of common stock underlying the
      Warrant.
     
    Second
      Amended and Restated Operating Agreement of Front Range Energy, LLC among the
      members identified therein (as amended by Amendment No. 1 described
      below)
     
    On
      October 17, 2006, the Company became a party to a Second Amended and Restated
      Operating Agreement of Front Range Energy, LLC among the members identified
      therein (as amended by Amendment No. 1 described below) (the “Operating
      Agreement”). The Operating Agreement governs the rights and obligations of the
      members (“Members”) of Front Range. The Operating Agreement contains numerous
      customary provisions relating to rights and obligations of the Members, the
      authority of the manager (the “Manager”) and the manner in which Front Range is
      to be operated. 
     
    The
      Operating Agreement provides that Members may be subject to additional capital
      calls upon the approval of 2/3 of the Members requiring them to make additional
      cash contributions to Front Range. In the event that a Member fails to fulfill
      its capital call obligations, other Members may contribute pro rata and thereby
      obtain additional membership units. In the event that other Members do not
      contribute the entire amount of the capital call, the unpaid amount will
      constitute an ongoing obligation of the Member that failed to initially
      contribute. The Operating Agreement provides that each Member, by execution
      of
      the Operating Agreement, is deemed to have granted the Company a first and
      prior
      lien and security interest in such Member’s units as security for the payment of
      all required contributions by such Member.
     
    Cash
      distributions by Front Range are to be distributed first to all Members in
      an
      amount equal to the estimated federal and state income tax liability
      attributable to such Member’s proportionate share of the net taxable income of
      Front Range. The Manager’s determination of the amount of the minimum mandatory
      distribution is binding and conclusive on all Members. Cash distributions by
      Front Range, are to be distributed second to all Members in proportion to the
      percentage of outstanding units held by each Member but reduced by any amount
      distributed to that Member to cover its tax liability, as described above.
      All
      cash distributions are subject to the determination by the Manager that
      available cash exists in order to make such distributions after taking into
      account working capital needs, future expenditures and agreements to which
      Front
      Range is a party.
     
    There
      is
      to be one Manager of Front Range. Initially, the Manager is Daniel A. Sanders.
      The Manager is to be appointed by the holders of Class A Units of Front Range.
      Mr. Sanders holds 100% of all Class A Units and therefore controls who will
      act
      as Manager of Front Range. The Manager’s compensation for services to Front
      Range is to be determined by the Members. Mr. Sanders holds a majority of the
      outstanding membership units and therefore controls the compensation payable
      to
      the Manager. The Manager will not be liable to Front Range or any Member for
      any
      loss, damage, liability or expense suffered except in the case of fraud, gross
      negligence or willful or wanton misconduct. No Member is liable for any debt,
      obligation or liability of Front Range, except as provided in the Operating
      Agreement. The Operating Agreement provides customary indemnification provisions
      for the benefit of the Manager and the Members and their affiliates and
      representatives and agents.
     
     
    
     
    The
      Manager has broad discretion to operate Front Range and to execute agreements
      on
      its behalf. Certain matters require approval from at least 2/3 of the Members,
      including the sale or disposition of all or substantially all assets or any
      property other than in the ordinary course of business, the acquisition of
      property in any fiscal year having a value in excess of $300,000, the entering
      into a joint venture or partnership agreement, the entering into a merger or
      other reorganization, the borrowing of funds in any fiscal year in excess of
      $300,000, the lending of funds in any fiscal year in excess of $300,000 and
      the
      commencement of a voluntary case in bankruptcy. 
     
    Each
      Member is entitled to appoint a representative to act as a board member and
      who
      is to vote such Member’s membership units on matters requiring consent of the
      Members. The Manager is required to prepare an annual operating plan for the
      approval of the board members. The board members are entitled to review and
      comment on the proposed annual operating plan and following the plan’s approval
      by at least 2/3 of the board members, the Manager is to implement the plan
      and
      is authorized only to make expenditures and incur only the obligations provided
      therein.
     
    The
      Operating Agreement expressly provides that the Manager and Members may engage
      in other business activities, including those in competition with the business
      of Front Range. The Operating Agreement includes confidentiality obligations
      on
      the part of the Manager and Members. The Operating Agreement also provides
      that
      the Manager has no fiduciary duty to Front Range or to any Member, except to
      act
      in good faith, a general obligation of fair dealing with respect to property
      of
      Front Range and any duty expressly set forth in the Operating Agreement or
      any
      other written agreement.
     
    The
      Operating Agreement provides for restrictions on the Members’ transfer of their
      membership units, with certain customary exceptions, unless approved by at
      least
      a majority of the Members. Upon a proposed transfer of membership units by
      a
      Member, each other Member and Front Range have options to purchase those units
      on the same terms as the bona fide offer received by the proposed transferor.
      The Operating Agreement contains customary procedures for the Members and Front
      Range to exercise this option. The Operating Agreement also provides for the
      right of the Members and Front Range to purchase a Member’s membership units in
      the event that they become subject to involuntary transfer or upon death,
      termination, liquidation or dissolution of the Member. The purchase price for
      membership units subject to involuntary transfer is the fair market value of
      the
      units as agreed by the disposing Member and at least a majority of the other
      Members, and if they are unable to agree, as determined by a third-party
      appraiser.
     
    The
      Operating Agreement contains buy-sell provisions that allow the owners of the
      Class A Units or the owners of the Class B Units to collectively make a buy-sell
      offer to the other group. Following such offer, the other group is entitled
      to
      accept such offer or decline such offer and force the offering group to purchase
      its units at the same price and on the same terms and conditions as in the
      initial offer.
     
     
    
     
    The
      Operating Agreement contains preemptive rights in favor of the Members requiring
      Front Range to first offer new membership units pro rata to the existing
      Members. The Operating Agreement contains customary provisions relating to
      the
      exercise by Members of their preemptive rights.
     
    Amendment
      No. 1, dated as of October 17, 2006, of the Second Amended and Restated
      Operating Agreement of Front Range Energy, LLC to Add a Substitute Member and
      for Certain Other Purposes
     
    On
      October 17, 2006, the Company entered into an Amendment No. 1, dated as of
      October 17, 2006, of the Second Amended and Restated Operating Agreement of
      Front Range Energy, LLC to Add a Substitute Member and for Certain Other
      Purposes (the “Amendment”). The Amendment authorizes and approves the admission
      of PE California as a member of Front Range and causes PE California to be
      bound
      by all of the terms and conditions of the Operating Agreement. The Amendment
      also includes an amended Section 6.14 to the Operating Agreement that includes
      certain exclusions in order to facilitate the Company’s compliance with its
      disclosure obligations under applicable securities laws.
     
    Non-Competition
      Agreements dated as of October 17, 2006 by and among Pacific Ethanol, Inc.,
      Front Range Energy, LLC and each of the members of Eagle Energy,
      LLC
     
    On
      October 17, 2006, the Company entered into Non-Competition Agreements dated
      as
      of October 17, 2006 with Front Range and each of the members (the “Eagle
      Members”) of Eagle Energy (the “Non-Competition Agreements”). The
      Non-Competition Agreements provide that the Eagle Members may not compete with
      the business of Front Range for a period of two years within a fifty mile radius
      of Front Range’s ethanol production facility in Windsor, Colorado. The
      Non-Competition Agreements also provide non-disclosure and confidentiality
      obligations on the part of the Eagle Members and provide obligations prohibiting
      the diversion of business from or inducement of competition with the business
      of
      Front Range. In addition, the Non-Competition Agreements prohibit the Eagle
      Members from hiring, engaging or attempting to hire or engage any person who
      has
      been a consultant or employee of Front Range.
     
    (2) Amendment
      of Amended and Restated Ethanol Purchase and Sale Agreement with Front Range
      Energy, LLC
     
    Amendment
      to Amended and Restated Ethanol Purchase and Sale Agreement dated October 17,
      2006 between Kinergy Marketing, LLC and Front Range Energy,
      LLC
     
    On
      October 17, 2006, Kinergy Marketing, LLC (“Kinergy”), a wholly-owned subsidiary
      of the Company, entered into an Amendment to Amended and Restated Ethanol
      Purchase and Sale Agreement dated October 17, 2006 with Front Range. The
      Amendment amends a certain Amended and Restated Ethanol Purchase and Sale
      Agreement dated as of August 9, 2006 by and between Kinergy and Front Range
      (the
“Restated Agreement”). The Amendment is described immediately below and is filed
      herewith as Exhibit 10.7. The Restated Agreement is described below and is
      filed
      herewith as Exhibit 10.8. 
     
    The
      Amendment extends the initial term of the Restated Agreement from three years
      to
      a term ending May 31, 2013 with automatic renewals for additional one-year
      periods thereafter unless a party to the Restated Agreement delivers written
      notice of termination at least 60 days prior to the end of the original or
      renewal term.
     
    Amended
      and Restated Ethanol Purchase and Sale Agreement dated as of August 9, 2006
      by
      and between Kinergy Marketing, LLC and Front Range Energy,
      LLC
     
    On
      August
      9, 2006, Kinergy entered into an Amended and Restated Ethanol Purchase and
      Sale
      Agreement dated as of August 9, 2006 with Front Range. The Restated Agreement
      amended an underlying agreement first signed on August 31, 2005. The Restated
      Agreement was initially effective for three years with automatic renewals for
      additional one-year periods thereafter unless a party to the Restated Agreement
      delivers written notice of termination at least 60 days prior to the end of
      the
      original or renewal term. The Amendment described above extended the initial
      term to May 31, 2013 and includes the same renewal provisions. Under the
      Restated Agreement, Kinergy is to provide denatured fuel ethanol marketing
      services for the production facility. Kinergy is to have the exclusive right
      to
      market and sell all of the ethanol from the facility, an estimated 40 million
      gallons per year. Pursuant to the terms of the Restated Agreement, the purchase
      price of the ethanol may be negotiated from time to time between Kinergy and
      the
      owner of the ethanol production facility without regard to the price at which
      Kinergy will re-sell the ethanol to its customers. Alternately, Kinergy may
      pay
      to the owner the gross payments received by Kinergy from third parties for
      forward sales of ethanol (the “Purchase Price”) less certain transaction costs
      and fees. From the Purchase Price, Kinergy may deduct all reasonable
      out-of-pocket and documented costs and expenses incurred by or on behalf of
      Kinergy in connection with the marketing of ethanol pursuant to the Restated
      Agreement, including truck, rail and terminal costs for the transportation
      and
      storage of the facility’s ethanol to third parties and reasonable, documented
      out-of-pocket expenses incurred in connection with the negotiation and
      documentation of sales agreements between Kinergy and third parties (the
“Transaction Costs”). From the Purchase Price, Kinergy may also deduct and
      retain the product of 1.0% multiplied by the difference between the Purchase
      Price and the Transaction Costs. In addition, Kinergy is to split the profit
      from any logistical arbitrage associated with ethanol supplied by the
      facility.
     
    Item
      3.02. Unregistered
      Sales of Equity Securities.
     
    As
      described in Item 1.01 above, on October 17, 2006, the Company sold to Eagle
      Energy an aggregate of 2,081,888 shares of common stock as part consideration
      for the sale of 10,095 Class B Voting Units of Front Range, which amount
      represents approximately 42% of the outstanding membership interests of Front
      Range. The Company also sold to Eagle Energy a warrant to purchase 693,963
      shares of common stock at an exercise price of $14.41 per share as part
      consideration for the sale of the Class B Voting Units, as described above.
      The
      disclosures contained in Item 1.01 of this Report on Form 8-K are incorporated
      herein by reference. 
     
    Exemption
      from the registration provisions of the Securities Act of 1933 for the
      transactions described above is claimed under Section 4(2) of the Securities
      Act
      of 1933, among others, on the basis that such transactions did not involve
      any
      public offering and the purchasers were accredited investors and had access
      to
      the kind of information registration would provide. Appropriate investment
      representations were obtained, and the securities were or will be issued with
      restricted securities legends.
     
    
     
    Item
      5.02. Departure
      of Directors or Principal Officers; Election of Directors; Appointment of
      Principal Officers.
     
    (a) Not
      applicable.
     
    (b) Effective
      as of October 17, 2006, Frank P. Greinke resigned as a member of the Board
      of
      Directors of the Company.
     
    (c) Not
      applicable.
     
    (d) Effective
      as of October 17, 2006, the Board of Directors of the Company appointed Daniel
      A. Sanders as a member of the Board of Directors of the Company. Mr. Sanders
      is
      the Manager and majority Member of Front Range, which is a party to the
      agreements of Front Range described in Item 1.01 above. The disclosures in
      Item
      1.01 above are incorporated herein by this reference.
     
    Item
      9.01. Financial
      Statements and Exhibits.
     
    (a) Financial
      Statements of Businesses Acquired.
     
    None.
     
    (b) Pro
      Forma Financial Information.
     
    None.
     
    (c) Exhibits.
     
    
      
        
            
              |   | 
              
                   
                Number 
               | 
              
                   
                Description 
               | 
            
            
              |   | 
              
                   
                10.1 
               | 
              
                   
                Membership
                  Interest Purchase Agreement dated as of October 17, 2006 by and
                  among
                  Eagle Energy, LLC, Pacific Ethanol California, Inc. and Pacific Ethanol,
                  Inc. 
               | 
            
            
              |   | 
              
                   
                10.2 
               | 
              
                   
                Warrant
                  to Purchase Common Stock dated October 17, 2006 issued to Eagle
                  Energy,
                  LLC by Pacific Ethanol, Inc. 
               | 
            
            
              |   | 
              
                   
                10.3 
               | 
              
                   
                Registration
                  Rights Agreement dated as of October 17, 2006 by and between Pacific
                  Ethanol, Inc. and Eagle Energy, LLC 
               | 
            
            
              |   | 
              
                   
                10.4 
               | 
              
                   
                Second
                  Amended and Restated Operating Agreement of Front Range Energy,
                  LLC among
                  the members identified therein (as amended by Amendment No. 1 described
                  below) 
               | 
            
            
              |   | 
              
                   
                10.5 
               | 
              
                   
                Amendment
                  No. 1, dated as of October 17, 2006, of the Second Amended and
                  Restated
                  Operating Agreement of Front Range Energy, LLC to Add a Substitute
                  Member
                  and for Certain Other Purposes 
               | 
            
            
              |   | 
              
                   
                10.6 
               | 
              
                   
                Form
                  of Non-Competition Agreement dated as of October 17, 2006 by and
                  among
                  Pacific Ethanol, Inc., Front Range Energy, LLC and each of the
                  members of
                  Eagle Energy, LLC 
               | 
            
            
              |   | 
              
                   
                10.7 
               | 
              
                   
                Amendment
                  to Amended and Restated Ethanol Purchase and Sale Agreement dated
                  October
                  17, 2006 between Kinergy Marketing, LLC and Front Range Energy,
                  LLC 
               | 
            
            
              |   | 
              
                   
                10.8 
               | 
              
                   
                Amended
                  and Restated Ethanol Purchase and Sale Agreement dated as of August
                  9,
                  2006 by and between Kinergy Marketing, LLC and Front Range Energy,
                  LLC
                  (*) 
               | 
            
            
              |   | 
              
                 _________________ 
               | 
                | 
            
            
              |   | 
              
                 (*) 
               | 
              
                 Filed
                  as an exhibit to the Registrant’s current report on Form 8-K for August 9,
                  2006 filed with the Securities and Exchange Commission on August
                  15,
                  2006. 
               | 
            
        
       
     
    
     
    SIGNATURE
    
    Pursuant
      to the requirements of the Securities Exchange Act of 1934, the Registrant
      has
      duly caused this report to be signed on its behalf by the undersigned hereunto
      duly authorized.
     
     
    
      
          
            |   | 
              | 
              | 
          
          
            |  Date:
              October 23, 2006 | 
            PACIFIC
              ETHANOL,
              INC. | 
          
          
                | 
                | 
                | 
          
          
            |   | 
            By:   | 
            /s/ WILLIAM
              G. LANGLEY | 
          
          
            |   | 
            
               
             | 
          
          
            |   | 
            
               William
                G. Langley 
              Chief Financial
                Officer 
             | 
          
      
     
     
     
    
    
     
    EXHIBITS
      FILED WITH THIS REPORT
     
    
      
        
            
              | 
                   
                Number 
               | 
              
                   
                Description 
               | 
            
            
              | 
                   
                10.1 
               | 
              
                   
                Membership
                  Interest Purchase Agreement dated as of October 17, 2006 by and
                  among
                  Eagle Energy, LLC, Pacific Ethanol California, Inc. and Pacific
                  Ethanol,
                  Inc. 
               | 
            
            
              | 
                   
                10.2 
               | 
              
                   
                Warrant
                  to Purchase Common Stock dated October 17, 2006 issued to Eagle
                  Energy,
                  LLC by Pacific Ethanol, Inc. 
               | 
            
            
              | 
                   
                10.3 
               | 
              
                   
                Registration
                  Rights Agreement dated as of October 17, 2006 by and between Pacific
                  Ethanol, Inc. and Eagle Energy, LLC 
               | 
            
            
              | 
                   
                10.4 
               | 
              
                   
                Second
                  Amended and Restated Operating Agreement of Front Range Energy,
                  LLC among
                  the members identified therein (as amended by Amendment No. 1 described
                  below) 
               | 
            
            
              | 
                   
                10.5 
               | 
              
                   
                Amendment
                  No. 1, dated as of October 17, 2006, of the Second Amended and
                  Restated
                  Operating Agreement of Front Range Energy, LLC to Add a Substitute
                  Member
                  and for Certain Other Purposes 
               | 
            
            
              | 
                   
                10.6 
               | 
              
                   
                Form
                  of Non-Competition Agreement dated as of October 17, 2006 by and
                  among
                  Pacific Ethanol, Inc., Front Range Energy, LLC and each of the
                  members of
                  Eagle Energy, LLC 
               | 
            
            
              | 
                   
                10.7 
               | 
              
                   
                Amendment
                  to Amended and Restated Ethanol Purchase and Sale Agreement dated
                  October
                  17, 2006 between Kinergy Marketing, LLC and Front Range Energy,
                  LLC 
               | 
            
        
       
     
     
     
    8